The analysis of organic matter (OM) preserved in stalagmites is a growing field, but there have been few studies of biomarker compounds such as lignin phenols that are widely used in other palaeoenvironmental contexts. Here we present a preliminary qualitative study of the OM in six stalagmite samples from contrasting environments, using thermochemolysis in the presence of tetramethylammonium hydroxide (TMAH). The results indicate that a wide variety of products is preserved, including several potential lignin-derived compounds, but also that further research is needed to maximise compound recovery and allow the analysis of dissolved OM preserved in stalagmites to reach its full potential.