212143-23-2|Ruthenium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]dichloro[(1R,2R)-1,2-diphenyl-1,2-ethanediamine-kN1,kN2]-, (OC-6-13)-

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CAS: 212143-23-2

MF: C44H32P2.C14H16N2.Cl2Ru

MW: 1006.93872

Synonyms: Ruthenium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]dichloro[(1R,2R)-1,2-diphenyl-1,2-ethanediamine-kN1,kN2]-, (OC-6-13)-

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Jonathan M. J. Williams

Department of Chemistry University of Bath Claverton Down

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Ruthenium-catalysed transfer hydrogenation reactions with dimethylamine borane

Co-reporter: Tracy D. Nixon, Michael K. Whittlesey, Jonathan M.J. Williams

pp: 6652-6654

Publication Date(Web):7 December 2011

DOI: 10.1016/j.tetlet.2011.10.039

Dimethylamine–borane adduct has been used as the hydrogen source for the reduction of carbonyl compounds, imines, oximes, nitriles, nitroarenes and alkenes using [Ru(p-cymene)Cl2]2 as the catalyst.The reduction of a range of functional groups has been achieved by ruthenium-catalysed transfer hydrogenation using dimethlyamine borane as the reducing agent. Image for unlabelled figure

Ruthenium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]dichloro[(1R,2R)-1,2-diphenyl-1,2-ethanediamine-kN1,kN2]-, (OC-6-13)-

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Jonathan M. J. Williams

M K Whittlesey

Simon Doherty

Julian G. Knight