Co-reporter: Christopher C. Scarborough, Ilia A. Guzei and Shannon S. Stahl
pp: NaN2286-2286
Publication Date(Web):2009/02/13
DOI: 10.1039/B902460C
A chiral seven-membered N-heterocyclic carbene (NHC) has been synthesized from its phenol adduct (NHC-HOPh) by a novel base-induced α-elimination method, and its donor strength has been determined from the IR stretching frequencies of the NHC-Rh(CO)2Cl complex.
Co-reporter: Christopher C. Scarborough, Ilia A. Guzei and Shannon S. Stahl
pp: 2284-2286
Publication Date(Web):13 Feb 2009
DOI: 10.1039/B902460C
A chiral seven-membered N-heterocyclic carbene (NHC) has been synthesized from its phenol adduct (NHC-HOPh) by a novel base-induced α-elimination method, and its donor strength has been determined from the IR stretching frequencies of the NHC-Rh(CO)2Cl complex.
